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The special one-off performance is due to take place on November 2 at the Thompson-Boling Arena.
They'll be joined at the Mexico-based extravaganza by Derek Trucks, Susan Tedeschi and more.
Worsham recently released a duet with Combs, ‘How I Learned To Pray’, as part of his forthcoming ‘Compadres’ EP.
The country icon will host the 2023 Christmas special and will also receive a special award at the inaugural People's Choice Country Awards in September.
The country-rocker is auctioning off a signed Gibson ES-335 guitar, along with a personal guitar lesson with King himself.
The playful, uptempo track appears on the ‘Last Night’ hitmaker's 2023 album, ‘One Thing At A Time’.