The original track appears on Isbell's acclaimed new album, ‘Weathervanes’.
The Fall run of shows will take the alt-country favourite across the UK, Denmark, Norway, the Netherlands and Ireland.
The eagerly awaited new project is set to be released on November 3.
The much-loved song originally appeared on Stapleton's 2017 project, ‘From A Room: Volume 2’.
Elsewhere in the conversation, the Oklahoma native touched on a variety of topics, from the origins of his music career to Black Mirror.
The Tennessee singer-songwriter has been teasing the deluxe version of the project for a number of weeks now.