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The whiskey-drenched single currently sits at 14 on the Billboard Hot Country Songs chart.
Sunday's ceremony also featured performances from Luke Combs, Brandi Carlile and Kacey Musgraves.
The singer-songwriter's viral 2022 single is tipped to win the Grammy for Best Country Solo Performance at Sunday's ceremony.
In tandem with the announcement, Pearce released two new songs from the upcoming project.
The West Virginia native linked up with her fellow Appalachian artist for a special rendition of the classic song.
The new project features live recordings of ‘Lyin’ Low’, ‘Temporary Town’, Zach Bryan's ‘Crooked Teeth’ and more.