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Shania Twain, Jon Pardi, HARDY, Carrie Underwood and more will all be taking part in the star-studded ceremony.
The Canadian singer-songwriter's debut project is set to be released on April 28.
The playful, retro-inspired visuals follow Kelsea and her best friends as they transform into a trio of murderesses
Marty Stuart & His Fabulous Superlatives, Jim Lauderdale and more have been added to the already-announced roster of performers.
Barry Gibbons, Chuck Leavell, Paul Rodgers, Slash and Warren Haynes will also perform as part of the tribute, which will also honour Lynyrd Skynyrd's Gary Rossington, who passed away earlier this year.
The track is expected to feature on the West Virginia songsmith's upcoming album.