The steadily rising star pulled out the Jimmy Martin classic during the Fort Bend Country Fair & Rodeo in Rosenberg, TX.
Aptly, the performance took place at the Stillwater's Tumbleweed Dancehall and Concert Venue.
Jelly Roll also played his own set at the festival this past weekend (October 5-6) in Ocean City, MD.
Riley asked to be a part of the charity show after his tour-stop was cancelled, due to Hurricane Helene.
The duo are both from North Carolina, and will join forces for the benefit concert on October 26th.
The two commercial country juggernauts will be joined for the one-day event by Megan Moroney, Treaty Oak Revival, Dasha and Conner Smith.
