The much-loved song originally appeared on Stapleton's 2017 project, ‘From A Room: Volume 2’.
Elsewhere in the conversation, the Oklahoma native touched on a variety of topics, from the origins of his music career to Black Mirror.
The Tennessee singer-songwriter has been teasing the deluxe version of the project for a number of weeks now.
The singer-songwriter also confirmed she's already started work on the hotly anticipated project.
John Anderson has already been confirmed as a guest at the September 5th show.
Fans are hoping the latest untitled track will feature on Zach's upcoming album, ‘Writers and Fighters’.