Their dark ballad also won the duo the award for Visual Media of the Year ahead of the ceremony.
Cole Swindell nabs second ACM Award of the night for 'She Had Me at Heads Carolina.'
The Iowa prodigy took home the prize for New Female Artist of the Year ahead of the Texas ceremony.
With three nominations at tonight's ceremony, Cody Johnson took the stage for a special Willie Nelson tribute following the country icons 90th birthday celebration.
The much-loved band triumphed over the likes of Zac Brown Band, Midland and Little Big Town.
The Illinois native's performance came just a matter of hours before the arrival of his debut studio album, Religiously.