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The powerhouse vocal pairing take home their second consecutive win in the stacked cateorgy.
The bluegrass pioneers were presented with the accolade during Wednesday night's ceremony at The Ryman Auditorium.
The Kentucky up-and-comer takes the category at the 22nd Annual Americana Honors & Awards.
The folk-leaning crooner will also be performing across the UK, France, Germany and more next year.
Kane will also be joined by Bailey Zimmerman, Chris Young, LOCASH, Cole Swindell, RaeLynn and Parmalee.
The event unofficially kicked off the 2023 AMERICANAFEST.