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The showcase will also include performances from Ian Munsick, Jackson Dean, Corey Kent, Ashley Cooke, Chapel Hart and Kameron Marlowe.
The song was released as a Spotify Single ahead of Willie Nelson's 90th birthday celebration.
The Sneedville native's 36-song opus recently spent its eighth week at the top of the Billboard 200.
The traditional-leaning country singer released his eagerly anticipated new record on July 14.
Both Charles Wesley Godwin and Trampled By Turtles are due to support Zach Bryan on the US leg of his 2023 ‘Burn, Burn, Burn’ tour.
The Oklahoma songsmith is currently in the middle of his 2023 UK & Europe tour.