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Gorley joins the already-announced Lainey Wilson, Nate Smith and Dalton Dover.
The new track serves as the follow-up to Zimmerman's heartbroken ballad, ‘Get To Gettin’ Gone’, which he released on December 23.
The War and Treaty, Ricky Skaggs and more also performed on the all-new Opry stage.
The chart-topping duo took home the coveted gong for ‘Best Country Duo / Group Performance’.
The heartfelt single is taken from Combs’ 2022 Grammy-nominated album, Growin’ Up.
The motivational anthem, which appeared on Johnson's Human double-album, earns the Texan his first ever Grammy.