The ‘Thank God’ hitmaker arrived at the star-studded ceremony with five nominations.
The chart-topping anthem draws inspiration from Jo Dee Messina's 90s country hit, ‘Heads Carolina, Tails California’.
The vulnerable track appears on the British singer-songwriter's new album, Subtract.
The country legend took a brief break from co-hosting alongside Garth Brooks for the fiery performance.
Amidst an already jam-packed weekend of shows, CMA Fest announces "Cadillac Three & Friends" will take over Ascend Amphitheater on Friday, June 9.
The likes of Jordan Davis, Trisha Yearwood, Breland, Tyler Hubbard, Mickey Guyton, TJ Osborne and Keith Urban will also be handing out awards at tonight's event.