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The duo have collaborated on ‘Sunday Supper’ and ‘Jailbreak’.
The ‘A Lot More Free’ singer-songwriter was speaking ahead of his set at the Germany festival's Holler Stage.
The UK trio will be the first girl-group to represent the UK since 1999.
The uptempo offering follows Twinnie's much-loved February release, ‘Worst Kind of Crush’.
The chart-topping artist will be on hand at the festival, alongside stars like Lainey Wilson, Midland and more.
It follows another vulnerable unreleased song snippet, ‘Superman’, as Wallen finalises his new album, ‘I'm the Problem’.