The song will appear on the band's eagerly awaited new album, Weathervanes.
The two country music legends will present the eagerly awaited ceremony from Frisco, Texas on May 11.
The Texas crooner makes his debut on the hit talkshow on Thursday, March 30.
The moody, heartbroken single has also entered the Top 10 of Billboard's all-genre Hot 100 chart.
The Iowa native's 2022 single recently entered the Top 25 at Country Radio.
The fast-emerging country artist joins the already-announced Lainey Wilson, Megan Moroney, Dan + Shay and more at the Ohio festival.