They'll be joined by the likes of 49 Winchester, Flatland Cavalry, Ryan Bingham and Randy Houser.
The song appears on Pearce's acclaimed 2021 project, 29: Written in Stone.
HARDY, Lainey Wilson, Blake Shelton, Carrie Underwood, Kane Brown and Katelyn Brown are also still in contention for the Texas ceremony's biggest prize.
The track is expected to feature on Bryan's eagerly anticipated new album, Writers and Fighters.
The country prodigy is currently out on the road in support of Lily Rose.
Whether it was through colorful covers or their own originals, the set provided further evidence of two acts at the top of their games; showing how, single-handedly, they are helping to make bluegrass music cool again.